ThuliumV1, Main, Exploration, bibRecord, 001393

Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions

Identifieur interne : 001393 ( Main/Exploration ); précédent : 001392; suivant : 001394

Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions

Auteurs : V. N. Makhov [Estonie, Russie] ; T. Adamberg [Estonie] ; M. Kirm [Estonie] ; S. Vielhauer [Estonie] ; G. Stryganyuk [Allemagne]

Source :

Journal of luminescence [ 0022-2313 ] ; 2008.

RBID : Pascal:08-0285216

Descripteurs français

Pascal (Inist)
- Photoluminescence, Transition interdite, Rayonnement UV extrême, Trempe, Transition permise, Transition niveau énergie, Dopage, Addition thulium, Fluorure de lithium, Fluorure d'yttrium, LiYF4.
Wicri :
- topic : Dopage.

English descriptors

KwdEn :
- Allowed transition, Doping, Energy-level transitions, Extreme ultraviolet radiation, Forbidden transitions, Lithium fluoride, Photoluminescence, Quenching, Thulium additions, Yttrium fluoride.

Abstract

The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm³⁺ 5d-4f luminescence in LiYF₄:Tm³⁺ and Lu³⁺ 5d-4f luminescence in LuF₃ as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er³⁺ to Lu³⁺).

Affiliations:

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Le document en format XML

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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions</title>
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<author><name sortKey="Adamberg, T" sort="Adamberg, T" uniqKey="Adamberg T" first="T." last="Adamberg">T. Adamberg</name>
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<series><title level="j" type="main">Journal of luminescence</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Allowed transition</term>
<term>Doping</term>
<term>Energy-level transitions</term>
<term>Extreme ultraviolet radiation</term>
<term>Forbidden transitions</term>
<term>Lithium fluoride</term>
<term>Photoluminescence</term>
<term>Quenching</term>
<term>Thulium additions</term>
<term>Yttrium fluoride</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Photoluminescence</term>
<term>Transition interdite</term>
<term>Rayonnement UV extrême</term>
<term>Trempe</term>
<term>Transition permise</term>
<term>Transition niveau énergie</term>
<term>Dopage</term>
<term>Addition thulium</term>
<term>Fluorure de lithium</term>
<term>Fluorure d'yttrium</term>
<term>LiYF4</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
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<front><div type="abstract" xml:lang="en">The conditions for co-existence of emissions from spin-allowed and spin-forbidden 5d-4f transitions in rare earth ions and for thermal quenching of these emissions have been analyzed by taking Tm<sup>3+</sup>
 5d-4f luminescence in LiYF<sub>4</sub>
:Tm<sup>3+</sup>
 and Lu<sup>3+</sup>
 5d-4f luminescence in LuF<sub>3</sub>
 as examples. It is shown that temperature behavior of 5d-4f luminescence agrees with the common trends in decreasing energy splitting between the lowest high-spin and low-spin 5d levels as well as decreasing energy gap between the lowest 5d level and the bottom of the conduction band of the host crystal towards heavier rare earth ions (from Er<sup>3+</sup>
 to Lu<sup>3+</sup>
).</div>
</front>
</TEI>
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Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions

Interplay of spin-allowed and spin-forbidden 5d-4f luminescence from rare earth ions

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

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